Hi, Im just trying to understand the availability of volatiles in near earth objects.
Here is an example of a sort of rock that hits earth on occasion:
http://en.wikipedia.org/wiki/CI_chondrite#Chemical_composition
Note that it claims this type of meteorite is 17%-22% water by weight, but it is "tied up in water-bearing silicates". Im hazy on my chemistry but I think this is saying something along the lines of, sure it has lots of water, but so does concrete.
So what would be involved in extracting this water?
Get a very big aluminized Mylar bag with a transparent window.
Put asteroid inside and seal.
Erect large inflatable solar concentrator and focus on bag window.
Wait for volatiles to boil off and extract through a valve in the bag.
Continue heating asteroid until it melts.
Insert heat resistant pipe through another valve to the centre of the molten asteroid.
Flow high pressure nitrogen through pipe.
Blow a nice big bubble, leaving a thick shell.
Seal pipe, and allow to cool.
Cut holes for airlock, etc.
Outfit as habitat with excellent radiation protection.
Making the Portland cement:
"Portland cement clinker is made by heating, in a kiln, a homogeneous mixture of raw materials to a calcining temperature, which is about 1450 °C for modern cements. "
http://en.wikipedia.org/wiki/Portland_cement
So I would say up to 500 C should remove some water, 1000 C might remove most, and 1500 C should remove all.
)
Get a very big aluminized Mylar bag with a transparent window.
Put asteroid inside and seal.
Erect large inflatable solar concentrator and focus on bag window.
Wait for volatiles to boil off and extract through a valve in the bag.
Continue heating asteroid until it melts.
Insert heat resistant pipe through another valve to the centre of the molten asteroid.
Flow high pressure nitrogen through pipe.
Blow a nice big bubble, leaving a thick shell.
Seal pipe, and allow to cool.
Cut holes for airlock, etc.
Outfit as habitat with excellent radiation protection.
Get a very big aluminized Mylar bag with a transparent window.
Put asteroid inside and seal.
Erect large inflatable solar concentrator and focus on bag window.
Wait for volatiles to boil off and extract through a valve in the bag.
Continue heating asteroid until it melts.
Insert heat resistant pipe through another valve to the centre of the molten asteroid.
Flow high pressure nitrogen through pipe.
Blow a nice big bubble, leaving a thick shell.
Seal pipe, and allow to cool.
Cut holes for airlock, etc.
Outfit as habitat with excellent radiation protection.
If you've been following my line of reasoning lately, you'll agree that most of this technology is already at *cough* TRL6 *cough*.
haha.. I wonder if someone would complain about that..
Germany 40kW laser gun
But that brings up a good point. These smaller asteroids may be actual boulders? They wouldnt have much gravity to hold themselves together.

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So what would be involved in extracting this water?


Hi smoliarm,
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I think C1 Chondrite is in fact the term for the meteorite fragments that we find that I guess have gone through extreme heating on arrival.
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My (weak) understanding is they are hard to find because the asteroids they come from tend to explode when they hit our atmosphere, due to the volatiles they contain.
What I am really interested in is the amount of water available in asteroid material before it becomes a meteorite.
Here is a quote from that Keck paper that initially suggested capturing an asteroid:
A 500-t, carbonaceous C-type asteroid may contain up to 200 t of volatiles (~100 t water and ~100 t carbon-rich compounds), 90 t of metals (approximately 83 t of iron, 6 t of nickel, and 1 t of cobalt), and 200 t of silicate residue)
I admit it is probably risky to base my understanding on a single paper whose focus is not so much on space science as why we should give them 2.5 billion dollars
So, what the hell, give them these $B and let them fail water extraction 
And, once again, there are strong evidences suggesting that CI chondrites do not originate from asteroids. Therefore, it's not a good idea to use their composition to estimate result of asteroid capture mission.
Carbonaceous asteroids are the most compositionally diverse asteroids and contain a rich mixture of volatiles, complex organic molecules, dry rock, and metals. They make up about 20% of the known population, but since their albedo is low, they may be heavily biased against detection in optical surveys... yada yada
I do not know, how the authors got the above estimate of asteroid composition, but I can assure you it does not follow from meteorite data. All I can tell you -- they would have pretty hard time with reviewers and editors if they try to publish this in journals like EPSL or GCA.
Smoliarm: Do you agree with the Keck assessment?
Quote from: SmoliarmI do not know, how the authors got the above estimate of asteroid composition, but I can assure you it does not follow from meteorite data. All I can tell you -- they would have pretty hard time with reviewers and editors if they try to publish this in journals like EPSL or GCA.
As always, I'm not getting something. BTW, there's a poster around here who should read your comments. I wouldn't dream of "forcing" them to do so.
A 500-t, carbonaceous C-type asteroid may contain up to 200 t of volatiles (~100 t water and ~100 t carbon-rich compounds), 90 t of metals (approximately 83 t of iron, 6 t of nickel, and 1 t of cobalt), and 200 t of silicate residue)...
...Carbonaceous asteroid material similar to the CI chondrites is easy to ...
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I admit something's not adding up...

).
)Hi again, smoliarm.
What I get from your post is that I just totally screwed up assuming C1 Chondrites represented examples of these carbonaceous asteroids with high volatile content, but you are not specifically saying that those carbonaceous asteroids with some volatile content do not exist.
I really only leapt on this particular class because the Keck paper and the wiki article mentioned about 20% water content, and the wiki article gave the clue that it was not present as ice.
My true aim was to guess how hard it would be to extract the volatiles, and that involved determining what form the water was present in.
So...
Ignoring the C1 Chondrite confusion, what can you say about the presence of volatiles in NEOs such as might be within a small delta-V of our orbit. Any good references we can go and read?
it is pretty common confusion.However, there are phyllosilicates in chondrites, and in some cases these phyllosilicates are indeed the major components. Also, there are some hints, that phyllosilicates occur on low albedo asteroids. You may also see same peculiar words like "serpentine-group minerals, saponite, and chlorite" - there is no need to go into this chemistry.
Because, fortunately, there is a normal human word for all this stuff - CLAY.
But, in chondrites this is not like a wet clay from some river-bed, it is much more like clay in a BRICK, in some wall.
So, your question "how hard it would be to extract the volatiles?" transforms into "how hard it would be to extract the water from a brick?"
It is hard.
Well, a fired clay brick water content would depend on temperature it's fired- which can be below 1000 C.
More worrying, there seem to be two camps about the actual amount of water present in any form.


) are in similar form to Portland cement....
Here is one chemical analysis of the Orgueil type CI1 carbonaceous chondrites:
Olivine 7.2 % (by weight)
Troilite 2.1 %
Pyrrhotite 4.5 %
Magnetite 9.7 %
Saponite–serpentine 71.5 %
Ferrihydrite 5.0 %
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Out of the thousands of meteorites that have been studied, there are only 3 type CI1 chondrites that have been well characterized: Orgueil, Ivuna, and Alais.
So, if you are in for NEO hunt for asteroid capture, you have 6 / 60,000 chance to get something like CI.
I guess, slim is the right word.
Well, a fired clay brick water content would depend on temperature it's fired- which can be below 1000 C.
Chemically, this is only half-true.
The bitter (chemical) truth is: The remaining water content depends on temperature AND TIME.
Just because these rocks were baked for some 4.5 billion years -- even at T well below 500°C -- leaves little hope for theoretical 15% of water in clay minerals. It is a very long time. And it is a very little hope.
But merely dried clay which hasn't heated over 100 C or hydrated portland cement has a lot of water.
It's a bad idea to compare portland cement with clays - chemically.
In cements, water present in the form of crystallization water, e.g.:
CaO·2SiO2·3H2O
It is still in the form of *true* water molecules, and it is relatively easy to release.
In clays, it's a different story, not only because the decomposition T is higher, but also because at these temperatures water components in clays tend to react with something else instead of recombining in H2O:
phyllosilica(OH) + troilite + high T -> FeO + SO2 instead of H2O
phyllosilica(OH) + kamasite + high T -> FeO + NiO instead of H2O
phyllosilica(OH) + graphite + high T -> CO + CO2 instead of H2O
et cetera, et cetera...
Yes, heating pure phyllosilicates in a perfectly clean test tube will give you water. But heating of crashed asteroid material will provide you a disappointment - mostly.
And finally, about 1 % -- carbonaceous chondrites, which are the only ones to have significant carbon content, and therefore can be used for ISRU. One percet is not a lot, but it is still 100 times higher than 0.01%.
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Here is one chemical analysis of the Orgueil type CI1 carbonaceous chondrites:
Olivine 7.2 % (by weight)
Troilite 2.1 %
Pyrrhotite 4.5 %
Magnetite 9.7 %
Saponite–serpentine 71.5 %
Ferrihydrite 5.0 %
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Warren, you quoted MINERAL composition and called it "chemical analysis". do not confuse chemical and mineral compositions.

And finally, about 1 % -- carbonaceous chondrites, which are the only ones to have significant carbon content, and therefore can be used for ISRU
PS: the correct name for Ivuna-type is just "CI". There is no "type CI1 chondrites". CI1 is used for particular meteorite to show its type and metamorphic group (although all CIs belong to group 1).
) isn't it the case that "CI" refers to the "class" of meteorite, and the "1" refers to its petrological "type"? Also, according to some references, it's possible that CI's can grade into petrological type 2, whatever that is, and thus one could technically have CI2 meteorites, although the few that have actually been studied have all been CI1's....
By the way, what about Phobos and Deimos? Do they have water?
They concluded that it originates from the closest Mars moon, Phobos. I was there, in the conference room, and I can tell you that the general reaction was severe skepticism plus some fierce (and loud) sarcasm. I proudly note that I was not among critics; I liked the idea from the beginning. Not because Andrei was my dissertation advisor, I just liked the idea, although at the time it did sound crazy.
...the officials concluded it was a spy thing developed by CIA and smartly disguised by NASA as an innocent meteorite.
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OK, OK: I admit I flunked mineralogy class;
Grant would pay for one take only...Well, to be fair, there is probably some strong sampling bias going. My understanding is that (a) CI meteors tend to get blown to smithereens when they hit the atmosphere, and (b) CI meteorites don't hold up well to Earth weathering even if they survive the impact.
Well, if we really want to get technical () isn't it the case that "CI" refers to the "class" of meteorite, and the "1" refers to its petrological "type"? Also, according to some references, it's possible that CI's can grade into petrological type 2, whatever that is, and thus one could technically have CI2 meteorites, although the few that have actually been studied have all been CI1's....
(she has a record of making up funny stuff)They concluded that it originates from the closest Mars moon, Phobos. I was there, in the conference room, and I can tell you that the general reaction was severe skepticism plus some fierce (and loud) sarcasm. I proudly note that I was not among critics; I liked the idea from the beginning. Not because Andrei was my dissertation advisor, I just liked the idea, although at the time it did sound crazy.
So did you like the idea because of evidence others missed or because it would be cool. Liking an idea because of wishful thinking without evidence if nothing to be proud of even if it does turn out to be right.
Of course neither should one dismiss an idea just because it sounds crazy, if the evidence back it up.
Anyway, very cool story. That is indeed one lucky meteorite.
...the officials concluded it was a spy thing developed by CIA and smartly disguised by NASA as an innocent meteorite.
Our guys are pretty darn good, eh? You all missed the invisible one that they dropped only 100m away!
But what a great story! Thanks for sharing.
BUT, Russian generals - they did NOT miss the "invisible one" 
So, they ordered like battalion of KGB officers, and these poor guys SIEVED all the sand on TWO square miles of desert, in the heat of Yemen summer, two times...

So, they ordered like battalion of KGB officers, and these poor guys SIEVED all the sand on TWO square miles of desert, in the heat of Yemen summer, two times...
The story gets better and better!
Are you saying that they combed the desert?

@ smoliarm: the Kaidun meteorite story is fascinating. You should write it up as an article for the Space Review!


And they did not just comb the surface, they had to do it TWO feet deep, for TWO square miles.
And they did not just comb the surface, they had to do it TWO feet deep, for TWO square miles.
So you're saying, in the *cough* SpaceBalls *cough* documentary, those guys were complaining too much for combing the desert?
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On Phobos & Deimos composition:
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And they did not just comb the surface, they had to do it TWO feet deep, for TWO square miles.

And they did not just comb the surface, they had to do it TWO feet deep, for TWO square miles.
That's one and a half million cubic meters. At ten liters a second it would take five years.
How many people were working on than combing? What kind of machinery did they have to help.