We want as quick a mission as possible.
I respectfully disagree. However, since my knowledge is based on readings and I am not a NASA worker, I could be totally wrong with the following views;
1. Spending more time in space may yield additional benefits such as more time for science and additional man power time for ISS activities such as cargo transfers. The duration determination of a mission seems a complex issue with the influence of many fixed/dynamic factors. Shuttles were designed to stay up some time in space and MMOD vulnerability can be minimized.
2. Somehow, I felt that with Atlantis, MCC-H is reluctant to extend mission timelines while with Discovery/Endeavour they are happy to do so (both before the mission kicks off the ground and up in space). The main reasons might be Atlantis not having the SSTPS and due to that her missions are planned with less number of tasks (can someone verify this?). In case of STS-129, I remember even though Atlantis had extra Cyro margins to stay up longer, MCC-H did not extend the mission. Once the mission objectives are achieved, the main priority is to bring her home

.
3. However, as psloss had mentioned both STS-132 and 135 have now already been extended by a day. So it seems that NASA is pushing maximum with STS-135. The weather day extension seems to be not an option (also judging from the previous Atlantis missions, NASA may not extend the mission when she is up in space).
4. I wonder, whether an ISS-shuttle photo could be taken using the HST or any other appropriate satellite if the Soyuz does not work out? May be this is not possible? Can someone comment? Of course, even if possible, all the unique vantage point pictures might not be possible.
5. Finally, let’s hope that Atlantis kicks off the ground on the first opportunity (as she did with STS-129 and STS-132!). With some additional Cyro margins and other favorable factors, hope NASA can do the photo shoot (if STS-135 timeline is the most important issue to overcome). Being the last flight, NASA might also like to do additional educational/ PR activities during the mission as well.