I don't know but I presume most of the upper stage power is used to get lots of cargo up to a stable initial LEO.
That said, and this deserves to be repeated, that Ariane-5 was originally designed to launch a crewed space 'plane. Most of its design and capabilities are informed by that original purpose.
Now, an ATV question of my own... although it could also be considered an Ariane-5 question. I hypothetically have an ATV that I want to send to resupply a crewed space laboratory in either the EML-1 or EML-2 halo orbit. Can Ariane-5 do it as-is or will there need to be modifications? If so, what modifications are required?
I ask this question because one post-ISS 'plan-B' is for ESA to launch a twin-module ATV-derived lab, probably to LEO, as an interim destination. It occured to me that a similar vehicle sent to one of the EML points would do nicely as an initial place to go in the event of a 'flexible path' program strategy.
The ATV concept of operations is really good. (ESA has a lovely animation available at the bottom of
http://www.esa.int/SPECIALS/ATV/SEM7S1L26DF_0.html that shows it quite nicely.) Underlying the operations concept is a subtly elegant architecture for exploration.
It starts with Ariane, a launch system that justifies its own existence with its utility for non-exploration missions. Even though the ATV launcher has its own designation (Ariane V ES) and is a configuration slightly different than either the ECA or GS variants, it uses pretty much "stock" parts. That has to make it incredibly cost effective as a booster for exploration!
Could it get to an ATV to an EML point? The ES can take 21 mT to LEO, and a loaded ATV uses pretty much all of that capability. For ATV as an ISS resupply vehicle, 8 of the 21 mT is considered payload. But what if that 8 mT were all propellant for a trip to an EML point? Would a hypergolic engine have the Isp to provide the needed delta-v? Would an ion thruster?
I'm betting the answers are that a hypergolic engine with an Isp in the 300 range would not, but an ion thruster with an Isp in the 3000 range would.
What does the rocket equation say?
9.8 * 3 000 * ln(21 / (21 - 8 )) = 14 099.4486
Yes, an ion thruster could do the job with lots of margin.
Is there any quicker way? A powered lunar swing-by can get you from LEO to EML2 in 23 days with a delta-v budget of 3522 m/s.
3 522 / (9.8 * ln(21 / (21 - 8 ))) = 749.39101
No conventional engine is going to have an Isp anywhere near 750. So the question becomes, "Is a really slow trip to an EML point powered by an ion thruster OK?"