Ah, The Martian Way, Asimov. At least ice retrieval from Saturns rings. I doubt it would it’s practical to return ice to the inner Solar System due to deltav requirement. Use locally, sure. Methane from Titan, or gas from any atmosphere has been discussed on this site and I think the consensus is negative but I would have to search for those discussions.EDIT: I missed your reference to the surface of Titan. That is surely not an absolute requirement.
At one point it was thought that methane was a major component of Titan's atmosphere, so you have the scooping operations described in, e.g., Arthur C. Clarke's IMPERIAL EARTH. But in reality there's only about 1 percent methane, at least in the upper atmosphere, so it's harder to get (you'd have to scoop it out of the lakes or at least dive well down into the troposphere.)
There's lots of ice on Ceres and probably Vesta, no need to go all the way to Saturn for it.