Author Topic: Liquid fluoride thorium reactor  (Read 25089 times)

Offline john smith 19

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Re: Liquid fluoride thorium reactor
« Reply #20 on: 04/20/2014 09:49 pm »
Just a reminder that the US does have experience of a space reactor in the form of the SNAP 10a design.

http://en.wikipedia.org/wiki/SNAP-10A

With ZrH fuel and a NaK coolant it was a thermal spectrum reactor (important as fast reactors need higher enrichment to work). It produced 500W. With modern thermoelectric elements that would probably be 1Kw. Shifting to a Stirling generator that goes up to maybe 4Kw.

OTOH you could tap the heat directly and use it for things like cracking CO2 into CO and O2, base heating, cracking the Martian rust into Iron and O2, making "Marscrete" etc.
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Offline QuantumG

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Re: Liquid fluoride thorium reactor
« Reply #21 on: 04/20/2014 09:51 pm »
I read something recently which indicated everyone who is actually doing something with Thorium as a nuclear fuel is doing so with pebble-bed reactors and even liquid water reactors. Liquid salt reactors are more an Internet amazing people thing. Is that about right?
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Offline ArbitraryConstant

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Re: Liquid fluoride thorium reactor
« Reply #22 on: 04/20/2014 10:06 pm »
AFIK thorium is supposed to have a very good fuel to energy conversion ratio and very low quantity of wait/byproducts.
Just use HEU, same advantages. I guess this is news people don't want to hear.

I read something recently which indicated everyone who is actually doing something with Thorium as a nuclear fuel is doing so with pebble-bed reactors and even liquid water reactors. Liquid salt reactors are more an Internet amazing people thing. Is that about right?
More or less. I think China's building a 2 MW technology demonstrator. They're pursuing several new fuel cycles.

Isn't a LFTR a more likely choice for a surface reactor?
More likely than space anyway.

If you were building a colony on Mars and you sent a reactor from Earth, it would probably be HEU. Where you'd explore other technologies would be a reactor actually built on Mars.
« Last Edit: 04/20/2014 10:14 pm by ArbitraryConstant »

Offline Vultur

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Re: Liquid fluoride thorium reactor
« Reply #23 on: 04/20/2014 10:34 pm »
BTW if you're looking to run a sustainable self expanding colony you'll need to be able to do it with natural Uranium or Thorium, because enrichment is a major PITA, needing very specialized ITAR controlled stuff in large amounts.  :(
(my italics)

I don't see any reason why US technology transfer regulations would necessarily apply to a colony on another planet or asteroid, especially if the colony was not funded or mostly not funded by the US. Presumably Russia, China, and others have enrichment technology too...

(And I suppose there would actually be not much point in restricting such technology in space; if you can hit the Earth with a nuclear weapon from, say, an asteroid, you can hit it with a big chunk of asteroid material...)

EDIT: bold
« Last Edit: 04/20/2014 10:35 pm by Vultur »

Offline john smith 19

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Re: Liquid fluoride thorium reactor
« Reply #24 on: 04/20/2014 11:42 pm »
I don't see any reason why US technology transfer regulations would necessarily apply to a colony on another planet or asteroid, especially if the colony was not funded or mostly not funded by the US. Presumably Russia, China, and others have enrichment technology too...
You are mistaken if you think ITAR is solely a US thing. The I is for International as it's an international agreement. Other countries may apply it differently. That does not mean they don't apply it at all.
Quote
(And I suppose there would actually be not much point in restricting such technology in space; if you can hit the Earth with a nuclear weapon from, say, an asteroid, you can hit it with a big chunk of asteroid material...)
That's logical.

But the history of the US ITAR law (and the efforts to reform it) show that "logical" has rarely been a guiding principle.   :(

Personally I wonder if this thread would have been better starting with the question "What isthe best reactor for space or planetary use?"
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Offline ArbitraryConstant

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Re: Liquid fluoride thorium reactor
« Reply #25 on: 04/21/2014 01:51 am »
I don't see any reason why US technology transfer regulations would necessarily apply to a colony on another planet or asteroid, especially if the colony was not funded or mostly not funded by the US. Presumably Russia, China, and others have enrichment technology too...
You are mistaken if you think ITAR is solely a US thing. The I is for International as it's an international agreement. Other countries may apply it differently. That does not mean they don't apply it at all.
It's not an international agreement, it's US export restrictions, and it doesn't unilaterally ban nuclear technology.

The applicable international agreement would be the nuclear non-proliferation treaty, and it doesn't ban sales outright either. Countries like India that build weapons without being recognized as one of the weapons states are out, but under both international and US law, sales are possible. For example China is building AP-1000 reactors, an American design.

I don't think a Mars colony would have any issues getting any nuclear technology that might be useful. That's where we'd start talking about what nuclear technology if any was the best choice given the choices and given the limits of the Mars industrial base.

Offline Hanelyp

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Re: Liquid fluoride thorium reactor
« Reply #26 on: 04/22/2014 01:32 am »
A centrifuge should be able to substitute for a gravity field in most industrial processes, including a molten salt reactor.

Many of the qualities commonly attributed to thorium are more directly associated with a molten salt reactor.  For example, high fuel burn up comes from being able to continually remove reactor poisons and replace fissioned fuel.

The liabilities I see for a thorium molten salt reactor for a spacecraft are large minimum mass, and lower power density.  Also, natural thorium232 is a fertile fuel, like U238, and must be converted in a breeder before being used for fuel.  Minor issues for a fixed planetary power station, problems for a spacecraft.

Offline Adaptation

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Re: Liquid fluoride thorium reactor
« Reply #27 on: 04/22/2014 02:11 am »
ITAR  is export restrictions on information from the US to international parties.  In principle its a good thing in practice its a huge barrier to entry and massive money pit for any small US business who falls under its umbrella.  Even stuff like spacesuits and space toilets are restricted.  Companies who want to work with international partners have to pay us government minders to flow them around while over seas to make sure they are not divulging sensitive toilet technology at an incredible expense. 

This is some bat scat crazy north korean type of implantation.




Itar was also used to shut down defense distributed even though things in the public domain are exempt from itar and everything DD made was in the public domain. 

Offline john smith 19

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Re: Liquid fluoride thorium reactor
« Reply #28 on: 04/22/2014 08:46 pm »
ITAR  is export restrictions on information from the US to international parties.  In principle its a good thing in practice its a huge barrier to entry and massive money pit for any small US business who falls under its umbrella.  Even stuff like spacesuits and space toilets are restricted.  Companies who want to work with international partners have to pay us government minders to flow them around while over seas to make sure they are not divulging sensitive toilet technology at an incredible expense. 

This is some bat scat crazy north korean type of implantation.

Itar was also used to shut down defense distributed even though things in the public domain are exempt from itar and everything DD made was in the public domain.
Well they were arms and they their plans could (theoretically) be distributed outside the US --> ITAR.

Nuclear technology (which this definitely is) makes governments very twitchy.  :(

Personally I think if people want fission power systems to become accepted they have to operate unenriched,  and that's tough because so many nuclear engineers are trained only in light water reactor technology (whose primary design criteria was "will this work well to power a US Navy submarine," whereas a system designed from day one to support utilities would have made different choices ) which just does not work without enrichment.  :(

Returning to topic my instinct is this tech will only be relevant off Earth when people need the kind of power stations you see on Earth, IE GW sized. That's 10s of 1000s of people to support (or some serious industrial mfg hardware).

Until them most (all ?) space reactors will run with HEU (or "bomb grade" Uranium as I like to think of it) for compactness, and I don't see that being left in the hands of the private sector any time soon.
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Offline sheltonjr

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Re: Liquid fluoride thorium reactor
« Reply #29 on: 04/28/2014 02:29 pm »
Here is a real reactor that actually ran, and ran well with great load following characteristics. That shows the possibilities with a Molten Salt Reactor (MSR). Thorium only makes things more complicated requiring possibly two fluids and salt processing.

A MSR running on Highly Enriched Uranium (HEU) or even plutonium would make a great space reactor. Small size, High temperature, Load following. The only fuel processing required is to allow the Xenon and Krypton and other gases escape from the system as they are major neutron absorbers.

The reactor would only have enough fuel in the system to maintain criticality. NO EXCESS CRITICALITY. Due to the strong negative temperature coefficient of reactivity, No dump tanks are required. (While still prudent for an Earth based reactor). 50 gram pellets would be added every week to replace the fuel used.

The high temperature of the reactor and the cooling loop make the radiators a lot more efficient, though it will still require pretty big radiators.

Once loaded with fuel,  1 Kg will provide almost 2 years of power at full power generating 2.5 thermal MWatts and 1.25 MW of electrical power if required. It will not normally be at full power. This electrical power can be used anywhere in the solar system.

Space is hard, Trying to do space with limited power only makes it harder.  Having lots of power makes electric propulsion a lot more viable. HiPEP, VASIMR, Hall Effect thrusters etc…. More importantly, life support becomes easier to provide the air we breathe, food we eat and to keep our cabin comfortable.  High power sensor systems such as surface penetrating radars, and high power high bandwidth laser communications. Electromagnetic shielding to reduce radiation effects.

The US and UK have an overabundance of Plutonium with 99 & 112 MT each!!! I cannot think of a better use for it.

After 30 years of use, a space tug could dock with the power plant and drain the salt and replace it with a fresh salt or from another reactor that had been processed to removed the remaining fission products.

I would also develop supercritical CO2 turbines and power conversion technology to reduce the size and weight of converting all that heat to electricity.

Aircraft Reactor experiment Statistics:
Size:        3ft diameter, 3ft tall
Power:    2.5 MWatts Thermal
Fuel Temp:   1600F, 870C
Fuel:       177 lb of U235, 25 lb/ft3, 93.4% Enrichment
Fluid:      1153 lbs.
Fuel Usage:   1.5g/day at max power
Core Mass:   Approximately 6000 lbs, 2700 Kg

http://web.ornl.gov/info/reports/1955/3445603498221.pdf
« Last Edit: 04/28/2014 02:33 pm by sheltonjr »

Offline sdsds

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Re: Liquid fluoride thorium reactor
« Reply #30 on: 05/11/2014 03:01 am »
I read something recently which indicated everyone who is actually doing something with Thorium as a nuclear fuel is doing so with pebble-bed reactors and even liquid water reactors. Liquid salt reactors are more an Internet amazing people thing. Is that about right?

I somewhat trust this source, as Baroness Worthington is patron and trustee of the Weinberg Foundation.
http://www.the-weinberg-foundation.org/wp-content/uploads/2013/06/Thorium-Fuelled-Molten-Salt-Reactors-Weinberg-Foundation.pdf

Regarding molten salt reactors it says:
Quote
Current international research and development efforts are led by China, where a $350
million MSR programme has recently been launched, with a 2MW test MSR scheduled
for completion by around 2020.
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Offline sdsds

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Re: Liquid fluoride thorium reactor
« Reply #31 on: 05/12/2014 07:02 am »
I read something recently which indicated everyone who is actually doing something with Thorium as a nuclear fuel is doing so with pebble-bed reactors and even liquid water reactors. Liquid salt reactors are more an Internet amazing people thing. Is that about right?

I should partially retract what I wrote previously. The same source describes (in section 6.1.1) the molten salt reactor being prioritized in China. As QuantumG indicates, the fuel for that is in a pebble bed; the salt is used for cooling.

I'm unsure of the mechanics involved: apparently the pebbles move through the salt in the core. For zero g applications it isn't clear (to me at least) that approach will work....

The source indicates the Chinese are also pursuing a reactor design in which the fuel is dissolved in the molten salt, but that is being moved forward at a pace which puts it several years behind the pebble-based design.
« Last Edit: 05/12/2014 07:03 am by sdsds »
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Offline JasonAW3

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Re: Liquid fluoride thorium reactor
« Reply #32 on: 05/12/2014 02:06 pm »
I read something recently which indicated everyone who is actually doing something with Thorium as a nuclear fuel is doing so with pebble-bed reactors and even liquid water reactors. Liquid salt reactors are more an Internet amazing people thing. Is that about right?

I should partially retract what I wrote previously. The same source describes (in section 6.1.1) the molten salt reactor being prioritized in China. As QuantumG indicates, the fuel for that is in a pebble bed; the salt is used for cooling.

I'm unsure of the mechanics involved: apparently the pebbles move through the salt in the core. For zero g applications it isn't clear (to me at least) that approach will work....

The source indicates the Chinese are also pursuing a reactor design in which the fuel is dissolved in the molten salt, but that is being moved forward at a pace which puts it several years behind the pebble-based design.

I imagine that a slow centrifuge of the pebble bed, with the cooler moltant salts being injected into the center of the centrifuge and being withdrawn from the edge of the centrifuge, would likely be the best and most efficent way to do a Pebble Bed reactor in microgravity.
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Online Robotbeat

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Re: Liquid fluoride thorium reactor
« Reply #33 on: 05/12/2014 05:00 pm »
I read something recently which indicated everyone who is actually doing something with Thorium as a nuclear fuel is doing so with pebble-bed reactors and even liquid water reactors. Liquid salt reactors are more an Internet amazing people thing. Is that about right?
Yeah, but that's because putting some Thorium in an existing design is obviously way easier than designing a new reactor entirely. A molten salt reactor makes a lot of sense (i.e. isn't mere internet amazing peopleism), but to get there you have to do actual hard engineering work.
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Offline Rhyshaelkan

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Re: Liquid fluoride thorium reactor
« Reply #34 on: 11/13/2016 07:09 pm »
Necromancy!!

Liquid Flouride Thorium Reactors were well on their way till Nixon killed it for political favors. There is nothing standing in the way of LFTR except funding and regulations. Especially on another world like the Moon or Mars. Far away from regulations.

LFTR is everything Fusion wishes it could be.



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Offline Rei

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Re: Liquid fluoride thorium reactor
« Reply #35 on: 11/13/2016 08:31 pm »
Why HEU and not 239Pu?  239Pu has:

 * A higher energy release in easily captured fission fragments per fission event (175.8 vs. 169.1 MeV)
 * More energy in prompt neutrons (5.8 vs. 4.8 MeV) - although about the same energy difference in reverse for beta- (5.3 vs. 6.5 MeV). We'll ignore harder to capture energy like gamma, neutrinos, etc.
 * More neutrons per fission (2.88 vs. 2.43 for slow fission, 2.94 vs. 2.45 for fast fission), and thus significantly smaller mass required for criticality
 * The other main criticality aspect, cross sections, are similar - 235U is better at some energies, 239Pu at others (http://www.nndc.bnl.gov/sigma/getPlot.jsp?evalid=15337&mf=3&mt=18&nsub=10 http://www.nndc.bnl.gov/sigma/getPlot.jsp?evalid=15321&mf=3&mt=18&nsub=10)
 * Higher metal density (19.8 vs. 19.1 g/cm^3) and higher oxide density (11,5 vs 10,97 g/cm^3) at the same oxidation state.

Uranium is cheaper, but for space applications I'd think this nearly irrelevant; 239Pu isn't crazy expensive like 238Pu.  Plutonium (both metal and oxide) has a lower melting point that uranium, but not enough that I'd think it relevant, they're both very high.  Uranium has better thermal conductivity, but that's mostly an engineering design issue.
 
« Last Edit: 11/13/2016 08:32 pm by Rei »

Offline Hanelyp

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Re: Liquid fluoride thorium reactor
« Reply #36 on: 11/15/2016 03:31 am »
I have this crazy idea of a liquid fission core in a centrifuge, hydrogen propellant bubbling up through the liquid then out through a nozzle for a rocket.  One question is how much fuel gets picked up by the propellant flow.

Offline randomly

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Re: Liquid fluoride thorium reactor
« Reply #37 on: 11/15/2016 05:18 am »
HEU is preferred because of Launch failure risks and ease of handling. The minor energy differences are outweighed by other aspects of the reactor design. Breach of an unused HEU core presents little risk as radiation off of it is so low. Pu239 on the other hand is very nasty stuff. If you introduce a fragment of Pu into a glove box the decay events are so energetic that it blasts bits of Pu off the fragment and in a relatively short time the entire interior of the glove box is covered in highly radioactive Pu.

Minimum critical mass may not be that much of an advantage when your design is limited by the maximum energy density of the core that you can deal with, other factors are defining core dimensions. HEU also has larger margins of control-ability than Pu. Besides the safety factors an HEU reactor is probably a lot more cost effective than developing a Pu reactor given the current state of nuclear technology.

Offline randomly

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Re: Liquid fluoride thorium reactor
« Reply #38 on: 11/15/2016 06:09 am »
I read something recently which indicated everyone who is actually doing something with Thorium as a nuclear fuel is doing so with pebble-bed reactors and even liquid water reactors. Liquid salt reactors are more an Internet amazing people thing. Is that about right?
It's probably best to separate the two technologies.
 Molten salts can be use with any Nuclear fuel. Molten salts can be used as coolants in solid fuel reactors, replacing the water coolant loops. More interestingly molten salts can also be used in liquid fueled reactors in which the nuclear fuel is dissolved in the molten salt. There are numerous research and development  projects on different designs using molten salt fuels in US, Canada, Russia, France, Japan, and China.
 Some of these use Uranium fuels (U235,U238), Some are using spent light water fuel (U235,U238,Pu239)(Russia), and some are working on U233 designs (bred from Thorium). China is by far the leader in Thorium (U233) based MSR, with at least 700 engineers on the project last I heard.

Molten salt reactors are a pretty broad category, with a lot of very different designs and approaches, different fuel cycles, different salts, thermal neutron designs, epithermal designs, fast designs. Different approaches to removing fission fragments (or not).
Thorium has become heavily associated with MSRs, probably because it's the best suited reactor type to run a thorium based fuel cycle. Thorium is not itself a fuel, but a fertile isotope that can be converted to a usuable nuclear fuel (Uranium 233) through neutron absorption in a reactor. A thorium MSR is essentially a breeder reactor, making it's own fuel from spare neutrons in the core. It's actually a lot more complicated than that as you want the thorium to absorb one neutron and then it takes about a month (half life) for it to decay into U233. You don't want it to absorb a second neutron, so you have to remove it from the core and wait for it to decay. All this adds complications to the design. The advantages to thorium as a fuel source are several. One is availability, it's 3 times more common on earth than Uranium. On the other hand it is not geologically concentrated like Uranium, and there is no real shortage of uranium either so no real cost advantage there. The other thorium advantage is the actinides generated in a thorium reactor all have relatively short half lifes of 30 years or less, so the radioactivity of the spent fuel diminishes much more rapidly than U235/U238 fueled reactors and reach safe levels in only hundreds of years instead of hundreds of thousands.

The downsides are that U233 is a proliferation hazard like U239. It can be used in nuclear weapons. So you run into problems of how to safeguard that, or denature the material with U238 (which then negates the rapid decay of the waste products because of the actinides generated by the U238).

There are no clean all purpose solutions. Molten Salt Reactors are not tied to Thorium. But there are many large advantages to be had in the constellation of options they enable. Much better passive reactor safety, higher fuel efficiency, use of light water spent fuel as fuel, higher operating temperatures for chemical process use and higher efficiency electric power generation, lower costs, more scalable reactor sizes, better waste management, etc.

Offline Rei

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Re: Liquid fluoride thorium reactor
« Reply #39 on: 11/15/2016 09:48 am »
HEU is preferred because of Launch failure risks and ease of handling. The minor energy differences are outweighed by other aspects of the reactor design. Breach of an unused HEU core presents little risk as radiation off of it is so low. Pu239 on the other hand is very nasty stuff. If you introduce a fragment of Pu into a glove box the decay events are so energetic that it blasts bits of Pu off the fragment and in a relatively short time the entire interior of the glove box is covered in highly radioactive Pu. Minimum critical mass may not be that much of an advantage when your design is limited by the maximum energy density of the core that you can deal with, other factors are defining core dimensions. HEU also has larger margins of control-ability than Pu. Besides the safety factors an HEU reactor is probably a lot more cost effective than developing a Pu reactor given the current state of nuclear technology.

The main benefit above is not so much the energy difference but the much smaller quantity required to reach critical mass, aka you can make an efficient core at a smaller size.  Poor neutron efficiency within the core means greater need for reflector mass to compensate.   For most space applications, unless you're talking something like manned-scale VASIMR missions, you don't need GW-scale reactors.  Also, minimum core size for efficient operation additionally comes into play when you're talking very long/high delta-V missions (Oort cloud and whatnot), which would call for a small core with a large fuel supply to be cycled through it, so as to maximize the fuel to core mass ratio. 

But I understand very well about how handling issues of nuclear fuels can make otherwise suboptimal choices into optimal ones.  If handling wasn't an issue we'd surely use 232U as a radioisotope fuel rather than 238Pu.  It undergoes a far longer, far more energetic decay chain over practical (~70yr) timeperiods, all the way down to lead, and is also cheaper to acquire (it's an unwanted contaminant in the thorium cycle). But it puts off some nasty gamma in its decay chain.  So it might be nice for using for something like Starshot where only miniscule quantities are required, but you wouldn't want to use it in multi-kilogram quantities to power a traditional probe.
« Last Edit: 11/15/2016 09:53 am by Rei »

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